A student dilutes 50 mL of a phosphoric acid-dihydrogen phosphate buffer solution to a final volume...

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Chemistry

A student dilutes 50 mL of a phosphoric acid-dihydrogenphosphate buffer solution to a final volume of 100 ml.

Will the pH of the buffer change noticeably? (Use Henderson-Hasselbeck conceptually )

For the same dilution above will the buffer capacity change?

Calculations: A 50.0 mL sample of a 0.100 M phosphoric acid,H3PO4 is titrated with 0.100 M NaOH.

Identify the major chemical species present and calculate the pHat these four points (first consider the titration curve)

Given : Ka (H3PO4)=7.5x10-3,Ka(H2PO4-)=6.2x10-8,Ka(HPO42-)=4.2x10-13

Point 1: after 20.0 mL of NaOH is added

Point 2: after 50.0 mL total of NaOH is added

Point 3: after 75.0 mL total of NaOH is added

Point 4: after 100.0 mL total of NaOH is added

Answer & Explanation Solved by verified expert
4.0 Ratings (494 Votes)
Will the pH of the buffer change noticeably Use Henderson Hasselbeck conceptually No since according to the equation pH pKa logConjugate base acid since this is a dilution to the same volume the    See Answer
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