12.      Predict the direction of the equilibrium shift when temperature is decreased in the following reactions: a.         C2H2 (g)...

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Chemistry

12.     Predict the direction of the equilibrium shift when temperature isdecreased in the following reactions:

a.        C2H2 (g) + H2O (g) ?CH3CHO (g)      [?H = -151kJ/mol]

b.        CH3CH2OH (l) + O2 (g) ?CH3CH2O (g) + H2O(g)      [?H = exothermic]

c.         2CH3CHO (g) ? 2 C2H4 (g) +O2 (g)      [?H =endothermic]

13.           Consider the following endothermic reaction for the production ofhydrogen gas in a rigid container:

CH4(g) + H2O(g)? CO(g) + 3 H2(g)

How will the yield of hydrogen changeif the equilibrium is disturbed by:

a.         Adding acatalyst.

b.         Increasing thepressure.

c.         Decreasing thetemperature.

d.         Adding inertargon gas.

e.         Increasing thetemperature.

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