Why is it that temperature fluctuations during atomization (i.e. in the plasma or flame) are a...

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Chemistry

Why is it that temperature fluctuations during atomization (i.e.in the plasma or flame) are a big problem for atomic emissionspectroscopy, but less of a problem for atomic absorbancespectroscopy? Include an equation in your answer.

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Influence ofFlame Temperature in Atomic Emission and Atomic Absorption FlameSpectrometryCurrently it is generally agreed that atomic absorption flamespectrometry is complementary rather than competitive to the oldermethod of flame emission spectrometry It is readily possible tocompare these two flame spectrometric methods because of thesimilarity in instrumentation necessary for measurementsComparison of these methods is often made but it appears that someconfusion exists as to the role of flame temperature in these flamespectrometric methods This confusion is particularly great whenreading some review articles on atomic absorption flamespectrometry 2 3 Therefore the influence of flame temperatureon the emission signal in atomic emission flame spectrometry and onthe absorption signal in atomic absorption flame spectrometry willbe considered in this manuscript The arguments mainly used See Answer

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