Using Le Châtelier's principle, explain how the addition of aqueous ammonia dissolves silver chloride. If HNO3...

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Chemistry

Using Le Châtelier's principle, explain how the addition ofaqueous ammonia dissolves silver chloride. If HNO3 isadded after the AgCl has dissolved in the NH3solution,it causes AgCl to re-precipitate. Explain by selecting all truestatements.

1.) AgCl is an insoluble solid.

2.) Ag+reacts with NH3 to formAg(NH3)2+, which \"adds\"Ag+ to the AgCl equilibrium, causing more AgCl todissolve.

3.) Ag+reacts with NH3 to formAg(NH3)2+, which \"removes\"Ag+ from the AgCl equilibrium, causing more AgCl todissolve.

4.) Adding HNO3, a strong acid, destroys the complexion and \"removes\" Ag+ from the AgCl equilibrium, causingAgCl(s) to re-form.

5.) Adding HNO3, a strong acid, destroys the complexion and \"adds\" Ag+ to the AgCl equilibrium, causingAgCl(s) to re-form.

6.) None of these.

Answer & Explanation Solved by verified expert
3.8 Ratings (533 Votes)
AgCl is a insoluble salt The saturated solution of AgCl in aqueous solution is represented by the following equilibrium AgCl s Agaq Cl aq1 Now if a solution of NH3 is added to the solution then NH3 reacts with the Ag ions to form the AgNH32 complex    See Answer
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