The Racah parameter B is 460 cm-1 in [Co(CN)6]3– and 615 cm-1 in [Co(NH3)6]3+. Consider the...

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Chemistry

The Racah parameter B is 460 cm-1 in [Co(CN)6]3– and 615 cm-1 in[Co(NH3)6]3+. Consider the nature of bonding with the two ligandsand explain the difference in the B value.

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When an atom has more than one electron there will be some electrostatic repulsion between those electrons The amount of repulsion varies from atom to atom depending upon the number and spin of the electrons and the orbitals they occupy The total repulsion can be expressed in terms of three parameters A B and C which    See Answer
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