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The initial steps in polymerization to form Prussian Blue is a photo-initiated reduction of Fe(III) to...

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Chemistry

The initial steps in polymerization to form Prussian Blue is aphoto-initiated reduction of Fe(III) to Fe(II).

i. This is a charge-transfer transition – what kind of chargetransfer transition is it, and what is oxidized?  

ii. A gas is released as the photo-sensitized mixture isirradiated. What is it?

iii. Why does reduction of the Fe(III) center make the complexmore labile? Explain in terms of CFSE.

Answer & Explanation Solved by verified expert
4.5 Ratings (704 Votes)
i This is a Metal to Ligand Charge TransferReaction in which FeII isOxidized ie electron density is transferredfrom FeII to    See Answer
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