Polarimetry Lab calculations: Isomer Observed Degree of Rotation(Raw data) (+) Carovene 158.75° (-) Carovene 229.75° Blank 200.75° Unknown (X) 175.25° I would like some help to...

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Chemistry

Polarimetry Lab calculations:

Isomer

Observed Degree of Rotation(Raw data)

(+) Carovene

158.75°

(-) Carovene

229.75°

Blank

200.75°

Unknown (X)

175.25°

I would like some help to figure out how to do this; I want tomake sure that I am doing it correct. Here is what I have done sofar:

  1. Find specific rotations for all the isomers:

I believe these are the equations to use:

X observed= X raw -Blank            l= 0.8 dm and c= 0.9600 g/cm3

[X]= X observed / lc

Can someone show me the calculations for all of them,this is what I did for Unknown:

My Unknown (X): I did x observed= 175.25-200.75=-25.5°

[X]= X observed / lc -25.5°/(0.8*0.9600)=-33.20°

  1. Find the Enantiomer Excess:

The equations our teacher gavewere:

EE= [X] observed /[X]pure * 100

([X]pure can be found by[X]= Xpure/ lc

I don’t know how to find x pure. What even is that,where can I get it from the numbers. After I get EE,

I need to find how much of (-) and (+) is in theenantiomer (the equation given for that is

EE= [X]+ XA +[X]- (1-X+)

[X]+ and [X]- aresupposed to be answers from number 1.

Answer & Explanation Solved by verified expert
4.3 Ratings (588 Votes)
Let X is the specific rotation of carovene X observed rotation lc given l 08 dm c 096 g cc lc 08 x 096 0768 X 15875 20075 0768 420768 547 0 similarly X the specific rotation of carovene    See Answer
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