Part A
Consider the second-order reaction:
2HI(g)→H2(g)+I2(g)
Rate law: k[H]^2
k= 6.4*10^-9 (mol*s) at 500 K
Initial rate = 1.6 * 10^-7 mol (l*s)
What will be the concentration of HI after t =3.65×1010 s ([HI]t) for a reaction startingunder this condition?
Part B
In a study of the decomposition of the compound X via thereaction
X(g)⇌Y(g)+Z(g)
the following concentration-time data were collected:
Time (min) | [X](M) |
0 | 0.467 |
1 | 0.267 |
2 | 0.187 |
3 | 0.144 |
4 | 0.117 |
5 | 0.099 |
6 | 0.085 |
7 | 0.075 |
Given that the rate constant for the decomposition ofhypothetical compound X from part A is 1.60 M−1⋅min−1,calculate the concentration of X after 14.0 min .
Part C
The following data were collected for the rate of disappearanceof NO in the reaction2NO(g)+O2(g)→2NO2(g):
Experiment | [NO](M) | [O2](M) | Initial Rate (M/s) |
1 | 0.0126 | 0.0125 | 1.41×10−2 |
2 | 0.0252 | 0.0250 | 1.13×10−1 |
3 | 0.0252 | 0.0125 | 5.64×10−2 |
What is the rate of disappearance of NO when [NO]=6.15×10−2 M and [O2]=1.75×10−2 M ?
Part D
What is the rate of disappearance of O2 at the concentrationsgiven in part (c)?
Part E
A certain reaction with an activation energy of 175 kJ/mol wasrun at 515 K and again at 535 K . What is the ratio of fat the higher temperature to f at the lowertemperature?
Usef=e^−Ea/(R⋅T)