Part A) Approximately how many mL of 5% BaCl2 solution would be required to precipitate all...

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Chemistry

Part A) Approximately how many mL of 5% BaCl2 solution would berequired to precipitate all the sulfate if we assume that yoursamples are pure Magnesium sulfate? Assume that the density of thebarium chloride solution is 1.00 g/mL.

Part B) If the samples were pure potassium sulfate would yourequire a smaller or larger volume of barium chloride solution thanthe amount calculated in (Part A) above?

Crucible/sample Number

1

2

3

Mass of unknown sample (g)

0.3623 g

0.3461 g

0.3607 g

Mass of crucibles (g)

32.6072 g

33.0450 g

32.4736 g

Mass of crucible + BaSO4 (g)

32.8294 g

33.2525 g

32.6823 g

Mass of BaSO4 (g)

0.2222 g

0.2075 g

0.2087 g

percentage of SO42-

25.2 %

24.7 %

23.8 %

Average Percentage

24.6 %

                                                           St Dev

0.709

Mass of Sulfate,

Trial 1) 0.0914 grams

Trial 2) 0.0854 grams

Trial 3) 0.0859 grams

These were determined by stiochemetric calculations

0.2222g x (1 mole BaSO4 / 233.39 g) x (1 mole sulfate / 1 moeBaSO4) x (96.0576 g Sulfate / 1 mole sulfate) = 0.0914grams SO42-

0.2075g x (1 mole BaSO4 / 233.39 g) x (1 mole sulfate / 1 moeBaSO4) x (96.0576 g Sulfate / 1 mole sulfate) = 0.0854grams SO42-

0.2087g x (1 mole BaSO4 / 233.39 g) x (1 mole sulfate / 1 moeBaSO4) x (96.0576 g Sulfate / 1 mole sulfate)= 0.0859 gramsSO42-

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Part A) Approximately how many mL of 5% BaCl2 solution would berequired to precipitate all the sulfate if we assume that yoursamples are pure Magnesium sulfate? Assume that the density of thebarium chloride solution is 1.00 g/mL.

Part B) If the samples were pure potassium sulfate would yourequire a smaller or larger volume of barium chloride solution thanthe amount calculated in (Part A) above?

Answer & Explanation Solved by verified expert
4.0 Ratings (773 Votes)
a The balanced chemical equation for the reaction between pure MgSO4 and BaCl2 is MgSO4 BaCl2 MgCl2 BaSO4 The molar ration of BaCl2 and BaSO4 is 11 The molar mass of BaSO4 is 23343 gmol    See Answer
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