Part A) Approximately how many mL of 5% BaCl2 solution would berequired to precipitate all the sulfate if we assume that yoursamples are pure Magnesium sulfate? Assume that the density of thebarium chloride solution is 1.00 g/mL.
Part B) If the samples were pure potassium sulfate would yourequire a smaller or larger volume of barium chloride solution thanthe amount calculated in (Part A) above?
Crucible/sample Number | 1 | 2 | 3 |
Mass of unknown sample (g) | 0.3623 g | 0.3461 g | 0.3607 g |
Mass of crucibles (g) | 32.6072 g | 33.0450 g | 32.4736 g |
Mass of crucible + BaSO4 (g) | 32.8294 g | 33.2525 g | 32.6823 g |
Mass of BaSO4 (g) | 0.2222 g | 0.2075 g | 0.2087 g |
percentage of SO42- | 25.2 % | 24.7 % | 23.8 % |
Average Percentage | 24.6 % |
                                                           St Dev | 0.709 |
Mass of Sulfate,
Trial 1) 0.0914 grams
Trial 2) 0.0854 grams
Trial 3) 0.0859 grams
These were determined by stiochemetric calculations
0.2222g x (1 mole BaSO4 / 233.39 g) x (1 mole sulfate / 1 moeBaSO4) x (96.0576 g Sulfate / 1 mole sulfate) = 0.0914grams SO42-
0.2075g x (1 mole BaSO4 / 233.39 g) x (1 mole sulfate / 1 moeBaSO4) x (96.0576 g Sulfate / 1 mole sulfate) = 0.0854grams SO42-
0.2087g x (1 mole BaSO4 / 233.39 g) x (1 mole sulfate / 1 moeBaSO4) x (96.0576 g Sulfate / 1 mole sulfate)= 0.0859 gramsSO42-
---------------------------
Part A) Approximately how many mL of 5% BaCl2 solution would berequired to precipitate all the sulfate if we assume that yoursamples are pure Magnesium sulfate? Assume that the density of thebarium chloride solution is 1.00 g/mL.
Part B) If the samples were pure potassium sulfate would yourequire a smaller or larger volume of barium chloride solution thanthe amount calculated in (Part A) above?