Much like the CO ligands, cyanide (CN-) ligands have IR stretching frequencies that are distinctive and...

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Chemistry

  1. Much like the CO ligands, cyanide (CN-) ligands haveIR stretching frequencies that are distinctive and therefore oftenparticularly useful. Consult an appropriate character table, andgive a reducible representation for the cyanide stretchingvibrations in the square-planar tetracyanoplatinate(II) ion,Pt(CN)42-.

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Answer CN is isoelectronic with CO and NO Both CO and CNcoordinate to the metal atom through carbon The free CN ion hasa stretching frequency of 2080 cm1 in    See Answer
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