Methane is a clean gaseous fuel used in chemical industries worldwide. 1000 kmol/hr of methane is...

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Chemistry


Methane is a clean gaseous fuel used in chemical industriesworldwide. 1000 kmol/hr of methane is combusted in a burner toprovide heat. The combustion reaction is:
CH4 + O2 à CO2 + H2O
Air is used for combustion and it can be assumed to becomposed of 20% oxygen and 80% nitrogen. Nitrogen is consideredinert and does not undergo any oxidation reaction.
The inlet pressure for all stream is atmospheric.
Use a conversion reactor in VMGSim simulation package tosimulate burner. Assume that the heat loss to surrounding isnegligible (very well insulated burner). Pressure drop across theburner is assumed to be 10 kPa. Assume adiabatic conditions withmethane conversion of 95%. Follow the simulation guideline (to beprovided) and having converged the simulation, export the resultsto WORD. The followings can be easily determined from theresults:
1- Properties of exhaust gases such as average specific heat,enthalpy, entropy, thermal conductivity, viscosity etc.
2- Composition of exhaust gases from the burner in mole% andmass%
3- The flow rate of each component in the exhaust gas inKg/h
4- Temperature of exhaust gases
5- Pressure of exhaust gases
6- Volumetric flow rate of gases
Now repeat the simulation assuming the you use 50% excess air.You need to increase the mole fraction in the inlet stream toburner. Keeping all other conditions the same, compare the resultsof the two simulation and answer the following questions in thereport. You may add these to the report (exported to WORD).
1- Is the final temperature lower or higher? Why?
2- Is there a change in reaction enthalpy? Explain.
3- Is there any change in specific heats?

Answer & Explanation Solved by verified expert
4.1 Ratings (707 Votes)
Given data Methane flowrate 1000 kmolhr Air inlet composition N2 80 and O2 20 Total conversion percentage 95 Total delp 10 kpa Pressure 1 atm Assumption for the simulation Inlet temperature 25 C Let us write down the balanced reaction CH4 2 O2 4N2 CO2    See Answer
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