In an experiment similar to this one, the solubility of potassium hydrogen oxalate (KHC2O4, molar mass=...

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Chemistry

In an experiment similar to this one, the solubility ofpotassium hydrogen oxalate (KHC2O4, molar mass= 128.13 g mol) isdetermined. A 5.0 10^-2 M aqueous solution of KCI is saturated withpotassium hydrogen oxalate. The following equilibrium results:KHC2O4(s)-----K^+ + HC2O4^-

Following saturation, the solution is filtered. Portions of thefiltered saturated solution are titrated with 0.1172M NaOHsolution.

The following date are obtained:

Volume of saturated KHC2O4 Solution Titrated, mL Determination#1 25.2 Determination #2 29.1

Volume of NaOH solution used, mL---------------------Determination #1 36.88 Determination #241.81

Temperature of saturated solution, C--------------------Determination #1 20.1 Determination #2 20.1

Calculate the following:

number of moles off NaOH needed, mol _______________________Forboth determinations

number of moles of HC2O4 ^- titrated,mol______________________For both determinations

[HC2O4^-] sat. sol'n_______________________________________Forboth determinations

[K^+]initial______________________________________________Forboth determinations

[K^+]from dissolved KHC2O4________________________________Forboth determinations

[K^+] sat. sol'n___________________________________________Forboth determinations

Ksp___________________________________________________For bothdeterminations

average Ksp

solubility of KHC2O3 in 5.0 x 10^-2M KCI, molL___________________for both determinations

Average solubility of KHC2O4 in 5.0 x 10^-2 KCI, mol L

solubility of KHC2O4 in 5.0 x 10^-2 M KCI, g per 100 mL

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