â€‹ Given the following reaction and thermodynamic data, what is a reccomended temperature for a 1 L...

90.2K

Verified Solution

Question

Chemistry

â€‹
Given the following reaction and thermodynamic data, what is areccomended temperature for a 1 L pilot scale reactor and how long(time) does it take for the reaction to take place?
CH3OCH2CH2CH2OCH2NH2 -> CH3OCH2CH2CH2OH + CH2=NH
Species
CH3OCH2CH2CH2OCH2NH2
CH3OCH2CH2CH2OH
CH2NH
Hf (Kcal/mol)
-91.15
-92.23
19.75
S (cal/mol/K)
118.08
97.18
54.18
300
39.13
29.37
8.92
400
48.84
36.69
10.39
500
56.65
42.77
11.99
600
63.34
48.03
13.47
800
74.69
56.74
15.95
1000
82.87
62.98
17.87
1500
0
0
21.02
Î”Hrxn (Kcal/mol)
Î”Srxn (cal/mol/K)
Î”Grxn (Kcal/mol)
Kp
18.67
33.28
8.69E+03
0.985534268
18.494
32.77367955
5.38E+03
0.993248201
18.292
32.31453957
2.13E+03
0.99785361
18.118
32.00460919
-1.08E+03
1.0009103
17.67
31.31834149
-7.38E+03
1.004656425
17.256
30.84797494
-1.36E+04
1.0068639
43.894
67.11038492
-5.68E+04
1.019230233
Kc
A-forward (sec^-1)
Ea(Kcal/mol)
K-forward (sec^-1)
0.001653304
2.10611E+14
53.09
4.40801E-25
0.001249683
2.80815E+14
52.914
3.42895E-15
0.001004382
3.51018E+14
52.712
3.18437E-09
0.000839549
4.21222E+14
52.538
3.06178E-05
0.000632018
5.61629E+14
52.09
3.295681283
0.000506726
7.02037E+14
51.676
3561.584427
0.000341966
1.05305E+15
78.314
4084.744896
Delta S+c (cal/mol/K)
A-backward (sec^-1)
K-backward (sec^-1)
-24.11856204
45429261.35
9.50818E-32
-23.54895154
59940560.67
7.31917E-22
-23.10712731
74049093.99
6.7176E-16
-22.74613063
87957142.2
6.39344E-12
-22.17652012
114260467
6.70489E-07
-21.73469589
139369642.5
0.000707053
-20.93187498
531011737.2
0.002059767

Answer & Explanation Solved by verified expert

4.2 Ratings (867 Votes)

The data shows that at 1500 degree Kelvin Kp is the highest 101923 compared to reaction at all other temperatures Even the delta G of the recation at 15000 K is most negative 568E04 See Answer

Get Answers to Unlimited Questions

Join us to gain access to millions of questions and expert answers. Enjoy exclusive benefits tailored just for you!

Membership Benefits:

Unlimited Question Access with detailed Answers
Zin AI - 3 Million Words
10 Dall-E 3 Images
20 Plot Generations
Conversation with Dialogue Memory
No Ads, Ever!
Access to Our Best AI Platform: Flex AI - Your personal assistant for all your inquiries!

Become a Member

Species	CH3OCH2CH2CH2OCH2NH2	CH3OCH2CH2CH2OH	CH2NH
Hf (Kcal/mol)	-91.15	-92.23	19.75
S (cal/mol/K)	118.08	97.18	54.18
300	39.13	29.37	8.92
400	48.84	36.69	10.39
500	56.65	42.77	11.99
600	63.34	48.03	13.47
800	74.69	56.74	15.95
1000	82.87	62.98	17.87
1500	0	0	21.02

Î”Hrxn (Kcal/mol)	Î”Srxn (cal/mol/K)	Î”Grxn (Kcal/mol)	Kp


18.67	33.28	8.69E+03	0.985534268
18.494	32.77367955	5.38E+03	0.993248201
18.292	32.31453957	2.13E+03	0.99785361
18.118	32.00460919	-1.08E+03	1.0009103
17.67	31.31834149	-7.38E+03	1.004656425
17.256	30.84797494	-1.36E+04	1.0068639
43.894	67.11038492	-5.68E+04	1.019230233

Kc	A-forward (sec^-1)	Ea(Kcal/mol)	K-forward (sec^-1)


0.001653304	2.10611E+14	53.09	4.40801E-25
0.001249683	2.80815E+14	52.914	3.42895E-15
0.001004382	3.51018E+14	52.712	3.18437E-09
0.000839549	4.21222E+14	52.538	3.06178E-05
0.000632018	5.61629E+14	52.09	3.295681283
0.000506726	7.02037E+14	51.676	3561.584427
0.000341966	1.05305E+15	78.314	4084.744896

Delta S+c (cal/mol/K)	A-backward (sec^-1)	K-backward (sec^-1)


-24.11856204	45429261.35	9.50818E-32
-23.54895154	59940560.67	7.31917E-22
-23.10712731	74049093.99	6.7176E-16
-22.74613063	87957142.2	6.39344E-12
-22.17652012	114260467	6.70489E-07
-21.73469589	139369642.5	0.000707053
-20.93187498	531011737.2	0.002059767