Explain the origin of d-d, metal-to-ligand charge transfer, and ligand-to-metal charge transfer transitions for octahedral metal complexes...

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Chemistry

Explain the origin of d-d, metal-to-ligand charge transfer, andligand-to-metal charge transfer transitions for octahedral metalcomplexes with appropriate molecular orbital diagrams. Also,comment on the allowance of these transitions using appropriateselection rules.

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The origin of d d Spectra For Octahedral complex the dd transition occur due toincompletely or partially filled d orbitalSelection rule a Spin selection rule For forbidden transitionS 0 Forallowed transitionS0 ie the transition are permitted between the state ofsame spin multiplicitySpin multiplicity S 2s1b Laporte or orbital selection See Answer

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