Draw and label crystal field splitting diagrams (including orbital labels) for the following complexes. Calculate he...

70.2K

Verified Solution

Question

Chemistry

Draw and label crystal field splitting diagrams (includingorbital labels) for the following complexes. Calculate he ligandfield stabilization energy as a factor of Delta for eachcomplex.
a. [Co(OH2)6]2+
b. [RH(NH3)6]2+
c. [NiCl4]2-

Answer & Explanation Solved by verified expert

4.0 Ratings (820 Votes)

First of all calculate the oxidation state of central atomAssume the oxidation state to be x for central metal and add thecharge of all other atoms present in complex This sum is equal tothe charge present present on the complex If no charge is presentthen sum is equal to zeroIn first complex central metal atom is cobalt 6 H2Oligands are attached to the complex So it is an octahedralcomplex In octahedral complex when ligands approach metal atomthe five degenerate d orbitals split into two sets namelyt2g and eg t2g is a triplydegenerate orbital and is of low energy whereas eg isdoubly degenerate orbital and is of high energy t2gorbital is lowered by 04 See Answer

Get Answers to Unlimited Questions

Join us to gain access to millions of questions and expert answers. Enjoy exclusive benefits tailored just for you!

Membership Benefits:

Unlimited Question Access with detailed Answers
Zin AI - 3 Million Words
10 Dall-E 3 Images
20 Plot Generations
Conversation with Dialogue Memory
No Ads, Ever!
Access to Our Best AI Platform: Flex AI - Your personal assistant for all your inquiries!

Become a Member