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At 25 C, you conduct a titration of 15.00 mL of a 0.0400 M AgNO3 solution...

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Chemistry

At 25 C, you conduct a titration of 15.00 mL of a 0.0400 M AgNO3solution with a 0.0200 M NaI solution within the followingcell:

Saturated Calomel Electrode || Titration Solution | Ag (s)

For the cell as written, what is the voltage after the additionof the following volume of NaI solution? The reduction potentialfor the saturated calomel electrode is E = 0.241 V. The standardreduction potential for the reaction

Ag+ + e- --> Ag(s)

is E0 = 0.79993 V. The solubility constant of AgI is Ksp = 8.3 x10^-17.

.600 mL = ______ V

10.30 mL= ______ V

30.00 mL= ______V

38.80 mL= ______V

Answer & Explanation Solved by verified expert
3.5 Ratings (567 Votes)
Given T 25 deg C 29815 K Volume of AgNO3 1500 mL AgNO3 00400 M NaI 00200 M Reduction potential of saturated calomel electrode 0241 V Ksp of AgI 83 E17 Solution We know from the cell Ecell EAgAg ESCE Lets use Nernst equation Ecell E0cell 00591 v n log 1Ag Lets use above given equation and write Ecell of overall reaction Ecell 079993 V 00591 V 1 log 1Ag Esce    See Answer
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