At 25 C, you conduct a titration of 15.00 mL of a 0.0400 M AgNO3 solution...

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Chemistry

At 25 C, you conduct a titration of 15.00 mL of a 0.0400 M AgNO3solution with a 0.0200 M NaI solution within the followingcell:
Saturated Calomel Electrode || Titration Solution | Ag (s)
For the cell as written, what is the voltage after the additionof the following volume of NaI solution? The reduction potentialfor the saturated calomel electrode is E = 0.241 V. The standardreduction potential for the reaction
Ag⁺ + e^- --> Ag(s)
is E0 = 0.79993 V. The solubility constant of AgI is Ksp = 8.3 x10^-17.
.600 mL = V
10.30 mL= V
30.00 mL= V
38.80 mL= V

Answer & Explanation Solved by verified expert

3.5 Ratings (567 Votes)

Given T 25 deg C 29815 K Volume of AgNO3 1500 mL AgNO3 00400 M NaI 00200 M Reduction potential of saturated calomel electrode 0241 V Ksp of AgI 83 E17 Solution We know from the cell Ecell EAgAg ESCE Lets use Nernst equation Ecell E0cell 00591 v n log 1Ag Lets use above given equation and write Ecell of overall reaction Ecell 079993 V 00591 V 1 log 1Ag Esce See Answer

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