An aqueous solution is 0.10 M in Na2SO4 and also 0.15 M in KBr. (a) What is...

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Chemistry

An aqueous solution is 0.10 M in Na2SO4and also 0.15 M in KBr.

(a) What is the ionic strength of the mixture?

(b) Which salt makes a greater contribution to the ionicstrength? Why?

(c) What impact does the ionic strength have on the activitycoefficients and activity of each ion? (i) both activitycoefficient and activity increase

           (ii) both activity coefficient and activity decrease

           (iii) activity coefficient decreases and activity increases

           (iv) activity decreases but activity coefficient increases

(d) Write the charge balance equation for this mixture.

(e) Write the mass balance equation for the acid systeminvolving the SO42 ̶ ion. Assume no ionpairing occurs.

Answer & Explanation Solved by verified expert
4.2 Ratings (723 Votes)
For 010 M Na2SO4 the ionic strength is 12Na12SO4222 120101202022 030 M The ionic strength for 015 M KBr is 12K12Br12 120151201512 015 M total 010 x 015 0015 M 2 that the unit for ionic strength is molarity but that a salts ionic strength need not match its molar    See Answer
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