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Agree that the derivative of entropy w/r to P at constant T is the negative of...

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Physics

Agree that the derivative of entropy w/r to P at constant T isthe negative of the product of volume and coefficient of thermalexpansion? And that therefore deltaS is negligible for liquids andsolids but can be quite substantial for gases? Please explainit!

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3.6 Ratings (585 Votes)
The temperature dependence of volume under constant pressure canbe transformed to the pressure dependence of entropy under constanttemperature through the Maxwell relation resulting in the volumethermal expansion coefficient V expressed asfollowswhere V is the    See Answer
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