A.) The equilibrium constant for the reaction A(g) ⇌B(g) is 102 . A reaction mixture initiallycontains [A] = 18.6 M and [B] = 0.0 M. Which statement is true atequilibrium?
| The reaction mixture contains [A] = 18.4 M and [B] = 0.2M. |
| The reaction mixture contains [A] = 0.2 M and [B] = 18.4M. |
| The reaction mixture contains [A] = 1.0 M and [B] = 17.6M. |
| The reaction mixture contains [A] = 9.30 M and [B] = 9.30M. |
B.) Determine the value of Kc for the followingreaction if the equilibrium concentrations are as follows:[H2]eq = 0.14 M, [F2]eq = 0.39 M, [HF]eq = 1.6M.
H2(g) + F 2(g) ↔ 2 HF(g)
| 3.4 × 10-2 |
| 29 |
| 8.7 × 10-2 |
| 47 |
| 2.1 × 10-2 |
C.) The equilibrium constant isequal to 5.00 at 1300 K for the reaction:
2 SO2(g) + O2(g) ↔ 2SO3(g).
If initial concentrations are [SO2] = 3.60 M,[O2] = 0.45 M, and [SO3] = 5.40 M, the systemis
| not at equilibrium and will shift to the left to achieve anequilibrium state. |
| not at equilibrium and will remain in an unequilibratedstate. |
| at equilibrium. |
| not at equilibrium and will shift to the right to achieve anequilibrium state. |
D.) The equilibriumconstant, Kp, equals 3.40 for theisomerization reaction:
cis-2-butene ↔ trans-2-butene.
If a flask initially contains 0.250 atm of cis-2-buteneand 0.165 atm of trans-2-butene, what is the equilibriumpressure of each gas?
| P(cis-2-butene) = 0.0458 atm andP(trans-2-butene) = 0.156 atm |
| P(cis-2-butene) = 0.0735 atm andP(trans-2-butene) = 0.250 atm |
| P(cis-2-butene) = 0.0485 atm andP(trans-2-butene) = 0.165 atm |
| P(cis-2-butene) = 0.0943 atm andP(trans-2-butene) = 0.321 atm |
E.) Consider the reactionSO2(g) +NO2(g) ↔ NO(g) +SO3(g) at 460°C.What is the equilibrium concentration of the SO3if the initial concentrations are[SO2] =[NO2] = 3.00 x10-3 M and [NO] =[SO3] = 4.00 x10-2 M? The valueof the equilibrium constant for the reaction is 85.0 at460°C.
| 7.72 x 10-3 M |
| 8.15 x 10-2 M |
| 4.20 x 10-3 M |
| 1.80 x 10-3 M |
| 4.56 x 10-2 M |
| 3.88 x 10-2 M |