(a) Consider the following two stage process: テつテつテつテつテつテつテつテつテつテつテつテつテつテつテつテつテつテつテつテつテつテつテつ Stage 1. The system absorbs 83 J of heat...

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Chemistry

(a) Consider the following two stage process:

テつテつテつテつテつテつテつテつテつテつテつテつテつテつテつテつテつテつテつテつテつテつテつStage 1. The system absorbs 83 J of heat and during this process ithad 44 J of work done on it.

テつテつテつテつテつテつテつテつテつテつテつテつテつテつテつテつテつテつテつテつテつテつテつStage 2. The system absorbs 63 J of heat and during this process itdoes 27 J of work on the surroundings.

テつテつテつテつテつテつテつテつテつテつテつテつテつテつテつテつテつテつテつテつテつテつテつCalculate Q, w, and テ寂戲 for the overall process

(b) A piston is compressed from a volume of 7.5 L to 2.2 L at aconstant pressure of 1.5 atm. During this process, the system alsoabsorbs 266 J of heat. Calculate テ寂戲 for this process.

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4.1 Ratings (825 Votes)

a). Total energy absorbs = 83+63 =146j

Q = 146J

w=44-27 = 17J ,テつテつ w is +ve sign because workdone on the system

テ寂戲= Q+w = 146 + 17 = 163 J.

b).Volume change = テ寂抃 = 7.5-2.2 = 5.3 L

テつテつテつテつテつテつテつテつテつテつテつテつテつテつテつテつテつテつテつテつテつテつテつテつテつテつテつテつテつテつテつテつ P = 1.5 atm

テつテつテつテつテつテつテつテつテつテつテつテつテつテつテつテつテつテつテつ W= Pテ寂抃 = 1.5 x 5.3 = 7.95 L-atm = 7.95 x 101.325J = 805.534 Jテつテつ ( 1 L-atm = 101.325J)

テつテつテつテつテつテつテつテつテつテつテつテつテつテつテつテつテつテつテつ Q = 266 J

テつテつテつテつテつテつテつテつテつテつテつテつテつテつテつテつテつテつテつテつテつテつテつテつテつテつテつ テ寂戲 = Q +W = 266 - 805.534 = - 539.534 Jテつテつテつテつテつテつテつテつテつテつ ( W is +ve because workdone onthe system)

テつテつテつテつテつテつテつテつテつテつテつテつテつテつテつテつテつテつテつテつテつテつテつ テ寂戲= - 539.5 J.

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