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9. Which of the following solutions has the greatest bufferingcapacity?

   [A] 0.243 M HF and 0.192 M NaF

   [B] 0.485 M HF and 0.383 M NaF

   [C] 0.970 M HF and 0.766 M NaF

   [D] 0.160 M HF and 0.126 M NaF  

   [E] They are all buffer solutions and would allhave the same capacity.

   10. The Henderson-Hasselbalch equation is________

   [A] pH = pK_a + log[acid]/[base]

   [B] [H⁺] = K_a +[base]/[acid]

   [C] pH = log [acid]/[base]

   [D] pH = pK_a - log[base]/[acid]

   [E] pH = pK_a + log[base]/[acid]

7. Calculate the pH of a solution prepared by dissolving 0.150mol of benzoic acid and 0.300

   mol of sodium benzoate in water sufficient to yield1.00 L of solution. The K_a of benzoic

   acid is 6.30 x 10^-5.

[A] 2.516 [B] 4.502 [C] 3.892 [D] 4.195 [E] 10.158

8. What change will be caused by addition of a small amount ofHCl to a solution containing

fluoride ions and hydrogen fluoride?

[A] The fluoride ions will precipitate out of solution as itsacid salt.

[B] The concentration of fluoride ion will decrease and theconcentration of hydrogen

fluoride will increase.

[C] The concentration of hydronium ions will increasesignificantly

[D] The concentration of hydrogen fluoride will decrease and theconcentration of

   fluoride ions will increase.

[E] The concentration of fluoride ions will increase as will theconcentration of hydronium

   ions.

11. The addition of hydrofluoric acid and ________ to waterproduces a buffer solution

[A] HF [B] KI [C] NaF [D] NaBr [E] NaNO₃