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1) Offer a reasonable explanation of why nitration of 1,4-dichlorobenzene yields mononitro derivative while N,N'diacetyl- 1,4Phenylene- diamine...

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Chemistry

1) Offer a reasonable explanation of why nitration of1,4-dichlorobenzene yields mononitro derivative while N,N'diacetyl-1,4Phenylene- diamine forms dinnitro compound.

2) Explain why p- nitrophenol is a stronger acid than phenolitself. Would P-methoxyphenol be a stronger or weaker acid thanphenol? Expain.

Answer & Explanation Solved by verified expert
3.6 Ratings (621 Votes)
Answer1Chlorine halogens shows 2 opposing effects viz R effect andI effect of which R being relatively effective activates thetowards electrophilic attack but unequally to ortho and paraposition There is more activation of para position than orthoposition as it has less I effect In 14Dichlorobenzene case paraposition is already occupied and only ortho position is availablefor electrophilic aromatic substitution But being less    See Answer
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