1. Add 0.5 mL of 0.10 M NiCl2 solution to each of 7 test tubes using...

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Chemistry

1. Add 0.5 mL of 0.10 M NiCl2 solution to each of 7 test tubesusing dropper provided. Label these tubes 1 through 7. 2. Add thefollowing to the respective tubes containing the NiCl2solution,

Tube 1: 5 drops of water (used here as a control experiment fordilution)

Tube 2: 1 mL of conc. HCl

Tube 3: 5 drops of conc. ammonia

Tube 4: 5 drops of dilute (5% v/v) ethylenediamine solution

Tube 5: 5 drops of 0.25 M C2O4 2- (oxalate) solution

Tube 6: 5 drops of 0.1 M SCN- (thiocyanate) solution

Tube 7: 5 drops of 0.1 M EDTA solution Mix each solutionthoroughly and be sure to note the colour of each tube.

3. Check the stability of each complex by adding 3-5 drops of 1M NaOH solution. Note any changes (e.g., formation of precipitate,colour change, etc.)

4. Add 0.5 mL of 0.10 M CuSO4 solution to each of 7 new testtubes labeled 8 through 14 using dropper provided. Repeat steps 2and 3.

The “field strength” of a ligand describes how strong thecoordination bond is, for a given metal and the ligand that isconsidered.  The field strength is evaluated byconsidering how much it causes the d orbitals to split (DE), whichof the ligands is strongest?  Which is theweakest?  Explain your choices in each case.

Answer & Explanation Solved by verified expert
4.4 Ratings (968 Votes)
Among the given ligands ethylene diamine is the strongest one and thiocyanate is the weakest one stronger ligands form inner orbital octahedral complexes after forcible pairing of electrons    See Answer
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