1) A. How does the following modifications affect the rate of a square planar substitution reaction? a)...

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Chemistry

1) A. How does the following modifications affect the rate of asquare planar substitution reaction?
a) changing the trans ligand from H- to Cl-
b) changing the leaving group from Cl- to I-;
C) adding a bulky substituent to a cis ligand,
d) increasing the positive charge on the complex.
B. Organometallic compounds are heavily used in catalysis. Writeout details of the reactions (including reaction cycle) in bothHydrogenation of alkanes with Wilkinsonâ€™s catalyst andHydroformulation with cobalt carbonyl catalyst (name the catalystin each case)

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4.3 Ratings (886 Votes)

Aawhen you observe the trans effect seriesCOCNC2H4PR2HMePhPyIBrClNH3Hydride ion lies higher than the chloride ionthus if the ligandtrans to H or Cl is the leaving group so the rate of substitutionwill be decreased if H is changed to ClbThe rate at which a See Answer

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